Dimethyl Sulfoxide → 6-Tert-butoxycarbonylamino-5-oxo-1,2,3,5,6,7,10,10a-octahydro-pyrrolo[1,2-a]azocine-3-carboxylic acid methyl ester

HRID 1204697Notes

Reaction equation

HRID 1204697 reaction equation
[CH3:1][O:2][C:3](=[O:4])[CH:5]1[N:6]([C:13]([CH:14]([CH2:15][CH:16]=[CH2:17])[NH:18][C:19](=[O:20])[O:21][C:22]([CH3:23])([CH3:24])[CH3:25])=[O:26])[CH:7]([CH2:10][CH:11]=[CH2:12])[CH2:8][CH2:9]1.[CH3:27][S:28]([CH3:29])=[O:30].[Cl:31][CH2:32][Cl:33]>>[CH3:1][O:2][C:3](=[O:4])[CH:5]1[N:6]2[CH:7]([CH2:8][CH2:9]1)[CH2:10][CH:17]=[CH:16][CH2:15][CH:14]([NH:18][C:19](=[O:20])[O:21][C:22]([CH3:23])([CH3:24])[CH3:25])[C:13]2=[O:26]

Participants

4

Reactant 3

HCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 235714265-Allyl-1-(2-tert-butoxycarbonylamino-pent-4-enoyl)-pyrrolidine-2-carboxylic acid methyl ester

Product 1

HCID 695843536-Tert-butoxycarbonylamino-5-oxo-1,2,3,5,6,7,10,10a-octahydro-pyrrolo[1,2-a]azocine-3-carboxylic acid methyl ester

Sources & evidence

ORD record
ord-172ed5fad9054a9da9953e03a7ef8ca4
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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