Methanol → [3-[Tert-butyl(dimethyl)silyl]oxy-4-(hydroxymethyl)cyclopentyl] methanesulfonate

HRID 1208794Notes

Reaction equation

HRID 1208794 reaction equation
[CH3:1][S:2](=[O:3])(=[O:4])[O:5][CH:6]1[CH2:7][CH:8]([CH2:19][O:20][CH2:21][c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)[CH:9]([O:11][Si:12]([CH3:13])([CH3:14])[C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:10]1.[CH3:28][OH:29].[H:30][H:31].[OH-:32].[OH-:34].[Pd+2:33]>>[CH3:1][S:2](=[O:3])(=[O:4])[O:5][CH:6]1[CH2:7][CH:8]([CH2:19][OH:20])[CH:9]([O:11][Si:12]([CH3:13])([CH3:14])[C:15]([CH3:16])([CH3:17])[CH3:18])[CH2:10]1

Participants

6

Reactant 5

HCID 887MethanolHCID 961Hydroxide2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 87157015HCID 87157015, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 87157082[3-[Tert-butyl(dimethyl)silyl]oxy-4-(hydroxymethyl)cyclopentyl] methanesulfonate

Sources & evidence

ORD record
ord-a2fbeb6a9c9b4067a398725de637908f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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