Benzene → TBDMS ether

HRID 1224289Notes

Reaction equation

HRID 1224289 reaction equation
[Br-:36].[C:7]([CH3:8])([CH3:9])([CH3:10])[Si:11]([CH3:12])([CH3:13])[O:14][Si:15]([C:16]([CH3:17])([CH3:18])[CH3:19])([CH3:20])[CH3:21].[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:37][P+:38]([c:39]1[cH:40][cH:41][cH:42][cH:43][cH:44]1)([c:45]1[cH:46][cH:47][cH:48][cH:49][cH:50]1)[c:51]1[cH:52][cH:53][cH:54][cH:55][cH:56]1.[Cl:22][c:23]1[cH:24][c:25]([C:30]([CH2:31][CH2:32][OH:33])=[O:34])[cH:26][cH:27][c:28]1[Cl:29].[K+:6].[OH2:35].[cH:57]1[cH:58][cH:59][cH:60][cH:61][cH:62]1>>[C:7]([CH3:8])([CH3:9])([CH3:10])[Si:11]([CH3:12])([CH3:13])[O:14][Si:15]([C:16]([CH3:17])([CH3:18])[CH3:19])([CH3:20])[CH3:21].[CH2:1]=[C:30]([c:25]1[cH:24][c:23]([Cl:22])[c:28]([Cl:29])[cH:27][cH:26]1)[CH2:31][CH2:32][OH:33]

Participants

10

Reactant 8

HCID 241BenzeneHCID 259Bromide ionHCID 813Potassium CationHCID 962WaterHCID 74506TriphenylmethylphosphoniumHCID 590018TBDMS etherHCID 45749132-Methylpropan-2-olateHCID 18427500HCID 18427500, compound

Product 2

HCID 590018TBDMS etherHCID 98373163-(3,4-Dichlorophenyl)-3-buten-1-ol

Sources & evidence

ORD record
ord-63c4888ea6fb42c1b58a8e06267ca10d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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