Acetate → diethyl 5-benzoyl-2,3-dihydro-1H-pyrrolizine-1,1-dicarboxylate

HRID 123525Notes

Reaction equation

HRID 123525 reaction equation
[C:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)(=[O:8])[c:9]1[n:10]([CH2:14][CH2:15][CH:16]([C:17](=[O:18])[O:19][CH2:20][CH3:21])[C:22](=[O:23])[O:24][CH2:25][CH3:26])[cH:11][cH:12][cH:13]1.[C:43]([O-:44])(=[O:45])[CH3:46].[C:48]([O-:49])(=[O:50])[CH3:51].[C:52]([O-:53])(=[O:54])[CH3:55].[CH3:28][C:29](=[O:30])[O-:31].[CH3:32][C:33](=[O:34])[OH:35].[CH3:36][CH2:37][O:38][CH2:39][CH3:40].[Mn+3:47].[Na+:27].[OH2:41].[OH2:42]>>[C:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)(=[O:8])[c:9]1[n:10]2[c:11]([cH:12][cH:13]1)[C:16]([C:17](=[O:18])[O:19][CH2:20][CH3:21])([C:22](=[O:23])[O:24][CH2:25][CH3:26])[CH2:15][CH2:14]2

Participants

8

Reactant 7

HCID 175Acetate4×HCID 176Acetic AcidHCID 923Sodium ionHCID 962Water2×HCID 3283Diethyl EtherHCID 105130Manganese(3+)HCID 149751302-Benzoyl-1-[3,3-di(ethoxycarbonyl)propyl]pyrrole

Product 1

HCID 9928574diethyl 5-benzoyl-2,3-dihydro-1H-pyrrolizine-1,1-dicarboxylate

Sources & evidence

ORD record
ord-4dc552721ad5447cbc069f7079566f0e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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