HCID 21916921, compound → HCID 9907763, compound

HRID 1242690Notes

Reaction equation

HRID 1242690 reaction equation
[CH:1]1([CH2:4][S:5][C:6]2[CH:15]=[C:14]3[C:9]([CH:10]=[CH:11][CH:12]=[C:13]3[CH2:16][CH2:17][NH:18][C:19](=[O:24])[CH2:20][CH2:21][CH2:22][Cl:23])=[CH:8][CH:7]=2)[CH2:3][CH2:2]1.I([O-])(=O)(=O)=[O:26].[Na+]>>[CH:1]1([CH2:4][S:5]([C:6]2[CH:15]=[C:14]3[C:9]([CH:10]=[CH:11][CH:12]=[C:13]3[CH2:16][CH2:17][NH:18][C:19](=[O:24])[CH2:20][CH2:21][CH2:22][Cl:23])=[CH:8][CH:7]=2)=[O:26])[CH2:3][CH2:2]1

Participants

3

Reactant 2

HCID 21916921HCID 21916921, compoundHCID 23667635Sodium periodate

Product 1

HCID 9907763HCID 9907763, compound

Procedure

The product obtained in Example 43 (10 mmol) is added to an aqueous 0.5M sodium periodate solution (21 ml, 10.5 mmol) at 0° C. Stirring at 0–5° C. is carried out overnight. The solution is filtered and the filtrate is extracted with chloroform.

Workup

  1. filtrationThe solution is filtered
  2. extractionthe filtrate is extracted with chloroform

Sources & evidence

ORD record
ord-0f1bb61d4c1a471a93666056e643b0c5
Source dataset
uspto-grants-2006_10
Patent number
US07115752B2

Reaction notes

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