2-oxo-2H-1-benzopyran-7-yl 4-[6-(2-methyl-acryloyloxy)-hexyloxy]-benzoate → 2-Methylacrylic acid 6-(4-benzothiazol-2-yl-2,6-dimethoxyphenoxy)hexyl ester 4-[6-(methacryloyloxy)hexyloxy]benzoic acid 2-oxo-2H-chromen-7-yl ester

HRID 1243260Notes

Reaction equation

HRID 1243260 reaction equation
[S:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[C:2]1[C:10]1[CH:28]=[C:27]([O:29][CH3:30])[C:13]([O:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][O:21][C:22](=[O:26])[C:23]([CH3:25])=[CH2:24])=[C:12]([O:31][CH3:32])[CH:11]=1.[O:33]=[C:34]1[CH:43]=[CH:42][C:41]2[C:36](=[CH:37][C:38]([O:44][C:45](=[O:65])[C:46]3[CH:51]=[CH:50][C:49]([O:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][O:59][C:60](=[O:64])[C:61]([CH3:63])=[CH2:62])=[CH:48][CH:47]=3)=[CH:39][CH:40]=2)[O:35]1>>[O:33]=[C:34]1[CH:43]=[CH:42][C:41]2[C:36](=[CH:37][C:38]([O:44][C:45](=[O:65])[C:46]3[CH:51]=[CH:50][C:49]([O:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][O:59][C:60](=[O:64])[C:61]([CH3:63])=[CH2:62])=[CH:48][CH:47]=3)=[CH:39][CH:40]=2)[O:35]1.[S:1]1[C:5]2[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=2[N:3]=[C:2]1[C:10]1[CH:11]=[C:12]([O:31][CH3:32])[C:13]([O:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][O:21][C:22](=[O:26])[C:23]([CH3:25])=[CH2:24])=[C:27]([O:29][CH3:30])[CH:28]=1

Participants

3

Reactant 2

HCID 212518122-oxo-2H-1-benzopyran-7-yl 4-[6-(2-methyl-acryloyloxy)-hexyloxy]-benzoateHCID 695844192-Methylacrylic acid 6-(4-benzothiazol-2-yl-2,6-dimethoxyphenoxy)hexyl ester

Product 1

HCID 878994872-Methylacrylic acid 6-(4-benzothiazol-2-yl-2,6-dimethoxyphenoxy)hexyl ester 4-[6-(methacryloyloxy)hexyloxy]benzoic acid 2-oxo-2H-chromen-7-yl ester

Procedure

Compound 26 was prepared by copolymerisation of 2-Methylacrylic acid 6-(4-benzothiazol-2-yl-2,6-dimethoxyphenoxy)hexyl ester with 4-[6-(methacryloyloxy)hexyloxy]benzoic acid 2-oxo-2H-chromen-7-yl ester in a method analogous to the copolymerisation step of Compound 25.

Sources & evidence

ORD record
ord-bbcc5ba667164bb7aa430742b5f86860
Source dataset
uspto-grants-2006_10
Patent number
US07118787B2

Reaction notes

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