HCID 13099718, compound → HCID 13135811, compound

HRID 1244624Notes

Reaction equation

HRID 1244624 reaction equation
[F:1][C:2]1[CH:7]=[CH:6][C:5](/[CH:8]=[CH:9]/[C:10]2[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=2)=[CH:4][CH:3]=1>[Pd]>[F:1][C:2]1[CH:3]=[CH:4][C:5]([CH2:8][CH2:9][C:10]2[CH:11]=[CH:12][C:13]([NH2:16])=[CH:14][CH:15]=2)=[CH:6][CH:7]=1

Participants

3

Reactant 1

HCID 13099718HCID 13099718, compound

Product 1

HCID 13135811HCID 13135811, compound

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

In an analogous manner to that described in Example 36 b), the hydrogenation of (E)-1-fluoro-4-[2-(4-nitrophenyl)ethenyl]-benzene [Example 39 a)] using palladium on carbon (10%) as the catalyst yields the 4-[2-(4-fluoro-phenyl)-ethyl]-phenylamine as a light red solid; MS: n/e=216 (M+H)+.

Sources & evidence

ORD record
ord-b749d8439f4048ea889726db2e1f07ee
Source dataset
uspto-grants-2006_10
Patent number
US07122562B2

Reaction notes

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