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HRID1247876

反应详情

EQUATION

反应方程式

HRID 1247876 的结构方程式

REACTANTS

反应物

2
结构：N
HCID222

Ammonia gas

H3N

结构：Nc1c(S(=O)(=O)O)cc(Br)c2c1C(=O)c1ccccc1C2=O
HCID22628

1-Amino-4-bromo-9,10-dioxo-9,10-dihydroanthracene-2-sulfonic acid

C14H8BrNO5S

PRODUCTS

生成物

1
结构：Nc1cc(S(=O)(=O)O)c(N)c2c1C(=O)c1ccccc1C2=O
HCID77725

1,4-Diamino-9,10-dihydro-9,10-dioxoanthracene-2-sulphonic acid

C14H10N2O5S

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

It must be described as extremely suprising that the reaction of 1-amino-4-bromo-anthraquinone-2-sulphonic acid with ammonia in water under the reaction conditions employed, under pressure, should take place so uniformly and smoothly to give 1,4-diamino-anthraquinone-2-sulphonic acid, without the formation of significant amounts of 1-amino-4-hydroxy-anthraquinone-2-sulphonic acid, as reported in German Patent Specification No. 1,142,174.