HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Azide → HCID 14189837, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | HCID 13403518 | HCID 13403518 | — |
| Catalyst | Trioctylmethylammonium chloride | HCID 21218 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 14189837 | HCID 14189837 | 87.5% |
Reaction Steps
6.0 grams (35.5 mmoles) of the 2-chloro-3-methylmercapto-propionic acid methyl ester produced in Example 5 were stirred with 3.47 grams (53.4 mmoles) of sodium azide and 0.82 grams of Aliquat 336 in 15 ml of water for 7 hours at 45° C. After working up according to Example 2 there were obtained 5.44 grams (87% of theory) of 2-azido-3-methylmercapto-propionic acid methyl ester as an analytically pure material.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04523012 |
| Source dataset | uspto-grants-1985_06 |
| ORD ID | ord-e61855e4af5c4b25a5744a5910b82d9c |
| Source note | uspto-grants-1985_06 |