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HRID1248269

反应详情

EQUATION

反应方程式

HRID 1248269 的结构方程式

REACTANTS

反应物

2
结构：[N-]=[N+]=[N-].[Na+]
HCID33557

未命名化合物

结构：COC(=O)C(Cl)CSCC(=O)O
HCID14189835

[(2-Chloro-3-methoxy-3-oxopropyl)sulfanyl]acetic acid

C6H9ClO4S

PRODUCTS

生成物

1
结构：COC(=O)C(CSCC(=O)O)N=[N+]=[N-]
HCID14189839

[(2-Azido-3-methoxy-3-oxopropyl)sulfanyl]acetic acid

C6H9N3O4S

收率 88.3%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC.[Cl-]
催化剂HCID21218

未命名化合物

结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

1.00 gram (4.70 mmoles) of the 2-chloro-3-carboxymethylmercapto-propionic acid methyl ester produced in Example 9 was stirred with 0.46 gram (7.08 mmoles) of sodium azide and 0.10 gram of Aliquat 336 in 2 ml of water for 15 hours at 50° C. After working up according to Example 2 there were obtained 0.91 gram (88% of theory) of 2-azido-3-carboxymethylmercapto-propionic acid methyl ester as an analytically pure material.