1,4-Butanediol → HCID 86739745, compound

HRID 1248334Notes

Reaction equation

HRID 1248334 reaction equation
[CH:1](=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[CH2:14]([OH:19])[CH2:15][CH2:16][CH2:17][OH:18]>CC(C)=O>[CH2:14]([OH:19])[CH2:15][CH2:16][CH2:17][OH:18].[CH:1](=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 80641,4-ButanediolHCID 8194Dodecanal2×

Product 1

HCID 86739745HCID 86739745, compoundYield 36.1%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Conditions

Temperature
50 °C

Procedure

Dodecanal (5 g) was reacted with 1,4-butane diol (1 g) by warming the mixture to 50° C. in order to melt the dodecanal and then allowing it to cool to room temperature. The mixture went completely solid and was worked up as in Example 3 with acetone to yield the 1,4-butane diol/dodecanal adduct (1.1 g) M.Pt 51° C.

Workup

  1. temperatureto cool to room temperature

Sources & evidence

ORD record
ord-f240992ff07346c7a95c3048eb2b3479
Source dataset
uspto-grants-1985_06
Patent number
US04523038

Reaction notes

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