Triethoxymethylsilane → Triethoxymethylsilane

HRID 1248390Notes

Reaction equation

HRID 1248390 reaction equation
[CH2:1]([OH:7])/[CH:2]=[CH:3]/[CH2:4][CH2:5][CH3:6].[CH3:8][Si:9]([O:16][CH2:17][CH3:18])([O:13][CH2:14][CH3:15])[O:10][CH2:11][CH3:12]>>[CH2:1]([OH:7])[CH2:2]/[CH:3]=[CH:4]\[CH2:5][CH3:6].[CH3:8][Si:9]([O:10][CH2:11][CH3:12])([O:16][CH2:17][CH3:18])[O:13][CH2:14][CH3:15]

Participants

4

Reactant 2

HCID 16241TriethoxymethylsilaneHCID 53180422-Hexen-1-ol

Product 2

HCID 16241TriethoxymethylsilaneHCID 52811673-Hexenol

Procedure

0.4 Percent of a reaction product formed by reacting a single perfume (trans-2-hexenol) with methyl triethoxysilane in a molar ratio of 2:1, which was used in the foregoing Reference Example, and 0.9 percent of a reaction product formed from cis-3-hexenol and methyl triethoxysilane in a molar ratio of 2:1, were mixed with 98.7 percent of another perfume component to prepare a green apple type blend perfume. A fragrant article was prepared by impregnating the blend perfume into circular filter paper of 65 mm in diameter and 3 mm in thickness. The article was then volatilized at room temperature.

Workup

  1. custom0.4 Percent of a reaction product formed

Sources & evidence

ORD record
ord-6b6bf4f348bc41fbb7fc8c39285bc66f
Source dataset
uspto-grants-1985_06
Patent number
US04524018

Reaction notes

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