HCID 12900881, compound → HCID 11608251, compound

HRID 1248396Notes

Reaction equation

HRID 1248396 reaction equation
CO[C@H]1[C@H](O)[C@H](OC)COC1OC.C[O:15][C@@H:16]1[C@@H:23]([O:24][CH3:25])[C@@H:22]([O:26][CH3:27])[C@@H:21]([CH2:28][O:29]C)[O:20][CH:17]1[O:18][CH3:19].CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)OC1OC>>[CH3:25][O:24][C@H:23]1[C@H:22]([O:26][CH3:27])[C@@H:21]([CH2:28][OH:29])[O:20][CH:17]([O:18][CH3:19])[C@@H:16]1[OH:15]

Participants

4

Reactant 3

HCID 12900881HCID 12900881, compoundHCID 12900882HCID 12900882, compoundHCID 53768393HCID 53768393, compound

Product 1

HCID 11608251HCID 11608251, compound

Procedure

When it is subjected to methanolysis, it gives 1 mol each of methylglucoside, methylgalactoside, methylarabinoside and methylglucuronide. A completely methylated compound (C68H116O24) obtained by methylation of soyasaponin A2 with methyl iodide, dimethyl sulfoxide and sodium hydride gives 1 mol each of methyl 3,4-di-O-methylglucopyranoside, methyl 2,4-di-O-methylarabinopyranoside, methyl 2,3,4,6-tetra-O-methylgalactopyranoside and methyl 2,3,4,6-tetra-O-methylglucopyranoside as methylated sugar, and 1 mol of 3,22,24-tri-O-methyl soyasapogenol A as methylated sapogenol, when subjected to methanolysis after reduction.

Sources & evidence

ORD record
ord-0a411f7e812644daa7ad05be951bfcb3
Source dataset
uspto-grants-1985_06
Patent number
US04524067

Reaction notes

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