Formic Acid → HCID 20276923, compound

HRID 1248556Notes

Reaction equation

HRID 1248556 reaction equation
[CH2:1]=[C:2]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])[CH2:3][CH2:4][CH2:5][CH2:6][OH:7].[CH:13](O)=[O:14]>CCOCC>[CH:13]([O:7][CH2:6][CH2:5][CH2:4][CH2:3][C:2](=[CH2:1])[CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])=[O:14]

Participants

4

Reactant 2

HCID 284Formic AcidHCID 20276907HCID 20276907, compound

Product 1

HCID 20276923HCID 20276923, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

20 mM of 5-methylene-7,7-dimethyloctanol were esterified with 6 ml of concentrated formic acid. The reaction took place at room temperature, under nitrogen and by mixing the ingredients under stirring for 24 h. The mixture was taken up with ether, washed with 2N NaOH, then with water until neutrality. The desired product was obtained after drying, concentration and bulb distillation under reduced pressure.

Workup

  1. customat room temperature
  2. additionunder nitrogen and by mixing the ingredients
  3. washwashed with 2N NaOH

Sources & evidence

ORD record
ord-9647b950dc5543bb9e202bde9842adcf
Source dataset
uspto-grants-1985_06
Patent number
US04525298

Reaction notes

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