N,N-Diethylethylenediamine → HCID 13423372, compound

HRID 1248581Notes

Reaction equation

HRID 1248581 reaction equation
[CH2:1]([N:3]([CH2:7][CH3:8])[CH2:4][CH2:5][NH2:6])[CH3:2].[N+:9]([C:12]1[CH:31]=[CH:30][C:15]([C:16]2[O:17][C:18]3[C:23]([C:24](=[O:26])[CH:25]=2)=[CH:22][CH:21]=[CH:20][C:19]=3[C:27](Cl)=[O:28])=[CH:14][CH:13]=1)([O-:11])=[O:10]>C1C=CC=CC=1>[CH2:1]([N:3]([CH2:7][CH3:8])[CH2:4][CH2:5][NH:6][C:27]([C:19]1[CH:20]=[CH:21][CH:22]=[C:23]2[C:18]=1[O:17][C:16]([C:15]1[CH:30]=[CH:31][C:12]([N+:9]([O-:11])=[O:10])=[CH:13][CH:14]=1)=[CH:25][C:24]2=[O:26])=[O:28])[CH3:2]

Participants

4

Reactant 2

HCID 60993N,N-DiethylethylenediamineHCID 54555253HCID 54555253, compound

Product 1

HCID 13423372HCID 13423372, compoundYield 65.1%

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The same procedure as in Example 31 was performed employing 0.34 g of N,N-diethylethylenediamine and 4'-nitroflavone-8-carboxylic acid chloride (prepared from 1.00 g of 4'-nitroflavone-8-carboxylic acid and 1.40 ml of thionyl chloride) in 30 ml of benzene to give 0.78 g of yellow crystals, which were recrystallized from methanol as yellowish brown crystals, m.p. 207°-209° C.

Sources & evidence

ORD record
ord-38f8598b049648a19663e6dbb5d6c942
Source dataset
uspto-grants-1985_06
Patent number
US04525356

Reaction notes

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