HCID 20223994, compound → HCID 20224066, compound

HRID 1249417Notes

Reaction equation

HRID 1249417 reaction equation
[CH2:1]([S:7][C:8]1[C:25]([S:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])=[CH:24][C:23]2[C:22]3[C:17](=[CH:18][C:19]([S:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH3:46])=[C:20]([S:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH:21]=3)[C:16]3[C:11](=[CH:12][C:13](Br)=[C:14]([S:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])[CH:15]=3)[C:10]=2[CH:9]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]>CN1C(=O)N(C)CC1>[CH2:1]([S:7][C:8]1[C:25]([S:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32])=[CH:24][C:23]2[C:22]3[C:17](=[CH:18][C:19]([S:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH3:46])=[C:20]([S:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH3:39])[CH:21]=3)[C:16]3[C:11](=[CH:12][C:13]([S:7][CH2:8][CH2:9][CH2:10][CH2:23][CH2:22][CH2:21][CH:20]=[CH2:19])=[C:14]([S:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])[CH:15]=3)[C:10]=2[CH:9]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

3

Reactant 1

HCID 20223994HCID 20223994, compound

Product 1

HCID 20224066HCID 20224066, compound

Reagents, catalysts & solvents 1

HCID 66611,3-Dimethyl-2-imidazolidinoneSolvent

Procedure

A mixture of 400 mg of 2,3,6,7,10-pentakis-(hexylthio)-11-bromotriphenylene, 70 mg of sodium (7-octenyl)thiolate and 60 ml of DMEU is stirred for 3 hours at 90° under N2 and worked up in the usual manner, giving 2,3,6,7,10-pentakis-(hexylthio)-11-(7-octenylthio)-triphenylene.

Sources & evidence

ORD record
ord-4987f2631d2a42b596be81d4255ade03
Source dataset
uspto-grants-1986_12
Patent number
US04631143

Reaction notes

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