Ethylamine → HCID 13753901, compound

HRID 1249458Notes

Reaction equation

HRID 1249458 reaction equation
[CH3:1][C:2]([C:5]1[C:10](=[O:11])[N:9]([NH2:12])[C:8](SC)=[N:7][N:6]=1)([CH3:4])[CH3:3].[CH2:15]([NH2:17])[CH3:16]>>[NH2:12][N:9]1[C:10](=[O:11])[C:5]([C:2]([CH3:4])([CH3:3])[CH3:1])=[N:6][N:7]=[C:8]1[NH:17][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 6341EthylamineHCID 30479Metribuzin

Product 1

HCID 13753901HCID 13753901, compound

Procedure

A mixture of 150 g of technical metribuzin 200 g water and 100 g of 70% aqueous ethylamine was heated 90° for 7.0 hours in a stirred autoclave. The contents were cooled to room temperature, the solid filtered off and dried in a circulating air oven at 60°. The crude product was recrystallized from toluene to give 74 g of analytically pure product, m.p. 177°.

Workup

  1. temperaturewas heated 90° for 7.0 hours in a stirred autoclave
  2. filtrationthe solid filtered off
  3. customdried in a circulating air oven at 60°
  4. customThe crude product was recrystallized from toluene
  5. customto give 74 g of analytically pure product, m.p. 177°

Sources & evidence

ORD record
ord-a56ebcd1e19749028094a5f4a9818201
Source dataset
uspto-grants-1986_12
Patent number
US04632694

Reaction notes

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