Metribuzin → HCID 13753902, compound

HRID 1249459Notes

Reaction equation

HRID 1249459 reaction equation
[CH3:1][C:2]([C:5]1[C:10](=[O:11])[N:9]([NH2:12])[C:8](SC)=[N:7][N:6]=1)([CH3:4])[CH3:3]>O.C(N)(C)C>[NH2:12][N:9]1[C:10](=[O:11])[C:5]([C:2]([CH3:4])([CH3:3])[CH3:1])=[N:6][N:7]=[C:8]1[NH:6][CH:5]([CH3:10])[CH3:2]

Participants

4

Reactant 1

HCID 30479Metribuzin

Product 1

HCID 13753902HCID 13753902, compound

Reagents, catalysts & solvents 2

HCID 962WaterSolventHCID 6363IsopropylamineSolvent

Procedure

A mixture of 20 g of technical metribuzin in 75 ml water and 28 ml isopropylamine was refluxed with stirring for 72 hours. The reactants were cooled and the solid product was isolated by filtration and drying. The m.p. was 158° and the structure was confirmed by elemental analysis and NMR analysis.

Workup

  1. temperaturewas refluxed
  2. temperatureThe reactants were cooled
  3. customthe solid product was isolated by filtration
  4. customdrying

Sources & evidence

ORD record
ord-6226bcf2bf384b2486a72126a10a4f12
Source dataset
uspto-grants-1986_12
Patent number
US04632694

Reaction notes

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