HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → HCID 53667290, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | HCID 54476628 | HCID 54476628 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 53667290 | HCID 53667290 | 50% |
Reaction Steps
A mixture of 9.6 g of methyl 2-(3-methylphenoxy)-3-methoxyacrylate, 8.0 g of N-bromosuccinimide and a catalytic amount of azobisisobutyronitrile was heated at reflux in carbon tetrachloride for 4 hours. After cooling, the solid was filtered, the filtrate evaporated, and purified by silica gel column chromatography to give methyl 2-(3-bromomethylphenoxy)-3-methoxyacrylate (6.5 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06337306B1 |
| Source dataset | uspto-grants-2002_01 |
| ORD ID | ord-3171868009ba422093f98ec46262c61f |
| Source note | uspto-grants-2002_01 |