Vinyl alcohol → Myristic Acid

HRID 1250412Notes

Reaction equation

HRID 1250412 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O:14]C[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O)=[O:13].[CH2:25]=[CH:26]O>>[C:12]([OH:14])(=[O:13])[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][CH2:25][CH3:26]

Participants

3

Reactant 2

HCID 11199Vinyl alcoholHCID 110462391,4-Anhydro-6-O-dodecanoyl-D-glucitol

Product 1

HCID 11005Myristic Acid

Conditions

Temperature
46 °C

Procedure

A 4% w/w dispersion was emulsified with 0.4% Span 20 and 1% w/w Mowiol 8-88 using a Silverson mixer. These 5 μm droplets also crystallised rapidly on cooling to 46° C. but it was noticeable under the microscope that in the presence of sonication the crystallisation rate within the droplets increased (crystallised within 10 sec).

Workup

  1. customThese 5 μm droplets also crystallised rapidly
  2. customit was noticeable under the microscope that in the presence of sonication the crystallisation rate within the droplets
  3. temperatureincreased
  4. custom(crystallised within 10 sec)

Sources & evidence

ORD record
ord-97670a047d884b3aacd6af684e0ef66c
Source dataset
uspto-grants-2002_01
Patent number
US06338742B1

Reaction notes

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