HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 13576833, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | HCID 13576795 | HCID 13576795 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 13576833 | HCID 13576833 | — |
Reaction Steps
To a stirred solution of the 9-acetyl compound (Example 4) (0.10 g) in ethanol (2 cm3) was added sodium borohydride (0.0075 g) with visible reaction. After 2 hours reaction was indicated to be complete. Water (20 cm3) and dichloromethane (20 cm3) were added and the mixture partitioned, the separated aqueous layer was re-extracted with dichloromethane (20 cm3) to give, after evaporating under vacuum, a yellow-white solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04742075 |
| Source dataset | uspto-grants-1988_05 |
| ORD ID | ord-6c8db1f08d6140b19f10568ea560de5d |
| Source note | uspto-grants-1988_05 |