Fomesafen → HCID 14182377, compound

HRID 1252642Notes

Reaction equation

HRID 1252642 reaction equation
[Cl:1][C:2]1[CH:24]=[C:23]([C:25]([F:28])([F:27])[F:26])[CH:22]=[CH:21][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:18]([O-:20])=[O:19])=[C:9]([CH:17]=1)[C:10]([NH:12][S:13]([CH3:16])(=[O:15])=[O:14])=[O:11].[O-][Cl:30].[Na+]>>[Cl:30][N:12]([S:13]([CH3:16])(=[O:15])=[O:14])[C:10](=[O:11])[C:9]1[CH:17]=[C:5]([O:4][C:3]2[CH:21]=[CH:22][C:23]([C:25]([F:27])([F:26])[F:28])=[CH:24][C:2]=2[Cl:1])[CH:6]=[CH:7][C:8]=1[N+:18]([O-:20])=[O:19]

Participants

3

Reactant 2

HCID 51556FomesafenHCID 23665760Sodium Hypochlorite

Product 1

HCID 14182377HCID 14182377, compound

Procedure

5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitro-N-methanesulfonyl benzamide, m.p. 215°-218° C. was chlorinated with "Clorox" (aqueous NaClO), following procedure I, to yield a product, m.p. 160°-161° (crystallizes from chloroform/ether).

Workup

  1. customto yield
  2. customa product, m.p. 160°-161° (crystallizes from chloroform/ether)

Sources & evidence

ORD record
ord-2f936f93acf04234975bdd16ecafd0c0
Source dataset
uspto-grants-1988_05
Patent number
US04744818

Reaction notes

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