2-Hydroxyethyl acrylate → HCID 20136850, compound

HRID 1253145Notes

Reaction equation

HRID 1253145 reaction equation
[CH3:1][O-:2].[CH2:3]([Sn+:7]([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:8][CH2:9][CH2:10][CH3:11])[CH2:4][CH2:5][CH3:6].[C:16]([O:20]CCO)(=[O:19])[CH:17]=[CH2:18]>>[CH2:1]([O:2][C:17](=[CH2:18])[C:16]([O-:20])=[O:19])[CH3:3].[CH2:12]([Sn+:7]([CH2:3][CH2:4][CH2:5][CH3:6])[CH2:8][CH2:9][CH2:10][CH3:11])[CH2:13][CH2:14][CH3:15]

Participants

3

Reactant 2

HCID 131652-Hydroxyethyl acrylateHCID 11964040Methoxytri-n-butylstannane

Product 1

HCID 20136850HCID 20136850, compound

Procedure

Tributyltin methoxide (5 g; 0.0155M) and 2-hydroxyethyl acrylate (1.8 g; 0.0155M) were mixed together in a round bottom flask which was then put on a rotary evaporator for 0.5 hr to strip off the methanol produced. 6.5 g (100% of theory) of the title compound was obtained. The product was subjected to infrared and NMR spectral analysis and the results are summarised in Table S1 below. In the NMR spectrum a small peak at δ=3.8 was observed which was assigned to residual unreacted tributyltin methoxide.

Workup

  1. customwas then put on a rotary evaporator for 0.5 hr
  2. customproduced

Sources & evidence

ORD record
ord-00ff3bd208ac436b8c2a83e3174d0c32
Source dataset
uspto-grants-1988_05
Patent number
US04748087

Reaction notes

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