HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cesium fluoride → Triphenylene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cesium fluoride | HCID 25953 | — |
| Reactant | Acetonitrile toluene | HCID 21584213 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Catalyst | Ferrocene-1,1'-bis-(diphenylphosphine) | HCID 635956 | — |
| Product | Triphenylene | HCID 9170 | — |
Reaction Steps
1-trifluoromethanesulfonato-2-trimethylsilylbenzene (3 equivalents) is reacted with 1 equivalent of the appropriate iodoaromatic (see scheme 5a), in the presence of 5 mol % of Pd(OAc)2, 5 mol % of dppf and 4 equivalents of CsF in toluene/acetonitrile, to obtain the desired ligands of the formulae IId), IIe) and IIf).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08455112B2 |
| Source dataset | uspto-grants-2013_06 |
| ORD ID | ord-dc6baef536d2463899c681964776dcd1 |
| Source note | uspto-grants-2013_06 |