Phenylglyoxal → HCID 57730109, compound

HRID 1253384Notes

Reaction equation

HRID 1253384 reaction equation
[C:1]1([C:7]([CH:9]=O)=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[NH2:11][C:12]1[C:13]2[C:18]([C:19]3[CH:20]=[CH:21][CH:22]=[CH:23][C:24]=3[C:25]=1[NH2:26])=[CH:17][CH:16]=[CH:15][CH:14]=2>C(O)C>[C:1]1([C:7]2[CH:9]=[N:26][C:25]3[C:12](=[C:13]4[CH:14]=[CH:15][CH:16]=[CH:17][C:18]4=[C:19]4[CH:20]=[CH:21][CH:22]=[CH:23][C:24]4=3)[N:11]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 14090PhenylglyoxalHCID 965649,10-Phenanthrenediamine

Product 1

HCID 57730109HCID 57730109, compoundYield 92%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

First, 2.16 g of phenylglyoxal and 3.36 g of 9,10-diaminophenanthrene were dissolved in a solvent of 100 mL of dehydrated ethanol under a nitrogen atmosphere. The solution was refluxed for 7 hours to be reacted. The white power precipitated through the reaction was filtered. The residue was washed with ethanol and then ether to give a dibenzo[f,h]quinoxaline derivative, Hdbq-P, which was the target substance (yield: 92%). Synthesis scheme of Step 1 is shown in (a-1) below.

Workup

  1. temperatureThe solution was refluxed for 7 hours
  2. customto be reacted
  3. customThe white power precipitated through the reaction
  4. filtrationwas filtered
  5. washThe residue was washed with ethanol

Sources & evidence

ORD record
ord-39532a2b992847c4ae3526acd742cae6
Source dataset
uspto-grants-2013_06
Patent number
US08455111B2

Reaction notes

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