HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triphenylphosphine → 3-Ethoxycarbonyl-1,1,1-triphenyl-6-(4-methylphenyl)-2-aza-1lambda5-phosphahexa-1,3,5-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Reactant | Ethyl (2Z,4E)-2-azido-5-(4-methylphenyl)penta-2,4-dienoate | HCID 12378027 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 3-Ethoxycarbonyl-1,1,1-triphenyl-6-(4-methylphenyl)-2-aza-1lambda5-phosphahexa-1,3,5-triene | HCID 86761121 | — |
Reaction Steps
Following General Procedure J, triphenylphosphine (1.5 g, 5.8 mmol) ethyl (2Z,4E)-2-azido-5-(4-methylphenyl)penta-2,4-dienoate (Compound 45, 1.5 g, 5.8 mmol) in diethyl ether (50 ml) were reacted to produce the title compound as a yellow solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07728014B2 |
| Source dataset | uspto-grants-2010_06 |
| ORD ID | ord-6b70e7d8fcb74f30a6fe09540ac7d36f |
| Source note | uspto-grants-2010_06 |