Pyridinium, 1-octyl-, bromide (1:1) → N-octylpyridinium tetracyanoborate

HRID 1255111Notes

Reaction equation

HRID 1255111 reaction equation
[C:1]([B-:3]([C:8]#[N:9])([C:6]#[N:7])[C:4]#[N:5])#[N:2].[K+].[Br-].[CH2:12]([N+:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]>>[C:1]([B-:3]([C:8]#[N:9])([C:6]#[N:7])[C:4]#[N:5])#[N:2].[CH2:12]([N+:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19]

Participants

3

Reactant 2

HCID 75674Pyridinium, 1-octyl-, bromide (1:1)HCID 23686396Potassium Tetracyanoborate

Product 1

HCID 86652229N-octylpyridinium tetracyanoborate

Procedure

Analogously to Example A, 83 g of potassium tetracyanoborate are added to 134 g of 1-octylpyridinium bromide, and the mixture is subjected to corresponding work-up, giving a clear, yellowish, viscous liquid.

Workup

  1. customgiving a clear, yellowish, viscous liquid

Sources & evidence

ORD record
ord-5bf21c595e2a4f489279a8a9a5dcf6e5
Source dataset
uspto-grants-2013_06
Patent number
US08455703B2

Reaction notes

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