HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl Alcohol → HCID 23186913, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl Alcohol | HCID 7858 | — |
| Reactant | 4-(Bromomethyl)benzoic acid | HCID 22599 | — |
| Reactant | Sodium hydride | HCID 24758 | — |
| Reactant | 4-But-3-enyloxymethyl-benzoic acid | HCID 22136996 | — |
| Product | HCID 23186913 | HCID 23186913 | — |
Reaction Steps
The reaction of allyl alcohol and 4-Bromomethyl-benzoic acid in the presence of sodium hydride was performed as described for Compound 33 to give 4-Allyloxymethyl-benzoic acid as white powder. 1H-NMR (400 MHz, d6-DMSO): 7.91 (d, J=8.3, 2 arom. H); 7.42 (d, J=8.3, 2 arom.H); 5.90 (m, —CHCH2); 5.30, 5.18 (2 d-like, —CH═CH2); 4.54 (s, —OCH2—C6H4); 4.01 (2 d-like, CH2═CHCH2O). 13C-NMR (100 MHz, d6-DMSO): 161.18 (—C═O); 143.48; 134.97; 129.95; 129.31 (2 arom.C); 127.11 (2 arom.C); 116.63; 70.64 (2 C).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08466199B2 |
| Source dataset | uspto-grants-2013_06 |
| ORD ID | ord-03bb24bae0054ee5940aba84f32d59ef |
| Source note | uspto-grants-2013_06 |