Allyl Alcohol → HCID 25056514, compound

Participants

Reaction Steps

The reaction of allyl alcohol and 3-chloromethyl-benzoic acid in the presence of sodium hydride was performed as described for Compound 37 to give 3-Allyloxymethyl-benzoic acid as colorless oil. 1H-NMR (400 MHz, d6-DMSO): 7.90 (m, 1 arom.H); 7.85 (m, 1 arom.H); 7.55 (m, 1 arom.H); 7.47 (m, 1 arom.H); 5.92 (m, —CH═CH2); 5.30, 5.16 (2 d-like, —CH═CH2); 4.52 (s, —OCH2—C6H4); 4.00 (d-like, CH2═CHCH2O). 13C-NMR (100 MHz, d6-DMSO): 167.24 (—C═O); 138.98; 135.04; 131.77; 130.80; 128.56; 128.34; 128.14; 116.60; 70.70; 70.55.

Provenance & Evidence