HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 59211739, compound → HCID 59211741, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 59211739 | HCID 59211739 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Isopropanol | HCID 3776 | — |
| Product | HCID 59211741 | HCID 59211741 | 54.4% |
Reaction Conditions
| Temperature | 100 °C |
|---|
Reaction Steps
3-Butylbicyclo[3.2.1]oct-6-en-2-one (100 g, synthesized as above) was placed in a stainless steel autoclave with isopropanol (50 g) and palladium on carbon (Pd/C, 1 g). The mixture was placed under 300 psi of hydrogen gas (H2) and heated at 100° C. until gas uptake ceased. The resulting material was removed from the autoclave, filtered, and distilled to yield 3-butylbicyclo[3.2.1]octan-2-one (55 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08466325B2 |
| Source dataset | uspto-grants-2013_06 |
| ORD ID | ord-c980926d654d47efa30827d965ae3542 |
| Source note | uspto-grants-2013_06 |