HRID1261706

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID22677185

未命名化合物

结构：CCCCCCCCCCCCC(CCCCCCCCCC)CN=C(O)c1c(Br)c(Br)c(C(O)=NCC(CCCCCCCCCC)CCCCCCCCCCCC)c2c(C(=O)O)c(Br)c(Br)c(C(=O)O)c12

HCID178442862

未命名化合物

PRODUCTS

生成物

结构：CCCCCCC(CCCCCC)CN=C(O)c1c(Br)c(Br)c(C(O)=NCC(CCCCCC)CCCCCC)c2c(C(=O)O)c(Br)c(Br)c(C(=O)O)c12

HCID178443157

未命名化合物

收率 22%

PROCEDURE

实验过程

The same synthetic method for compound 22 was used except using 2-hexyloctyl amine instead of 2-decyltetradecyl amine, and the yield was 22% (calculated based on TBNDA as a starting material).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-38709881cfc249cbaeb03b5526ab4ff5
来源数据集: uspto-grants-2013_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08471021B2
来源说明: uspto-grants-2013_06

反应 SMILES

[CH2:1]([CH:11]([CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68]CCCCCC)[CH2:12][N:13]=[C:14]([C:16]1[C:25]2[C:24]([C:26]([OH:28])=[O:27])=[C:23]([Br:29])[C:22]([Br:30])=[C:21]([C:31]([OH:33])=[O:32])[C:20]=2[C:19]([C:34](=[N:36][CH2:37][CH:38]([CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56]CCCC)[CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44]CCCCCC)[OH:35])=[C:18]([Br:61])[C:17]=1[Br:62])[OH:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]CCCC.C(C(CCCCCC)CN)CCCCC>>[CH2:51]([CH:38]([CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])[CH2:37][N:36]=[C:34]([C:19]1[C:20]2[C:21]([C:31]([OH:33])=[O:32])=[C:22]([Br:30])[C:23]([Br:29])=[C:24]([C:26]([OH:28])=[O:27])[C:25]=2[C:16]([C:14](=[N:13][CH2:12][CH:11]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH3:68])[OH:15])=[C:17]([Br:62])[C:18]=1[Br:61])[OH:35])[CH2:52][CH2:53][CH2:54][CH2:55][CH3:56]