HRID1261708

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID23053574

未命名化合物

结构：CCCCCCCCCCCCC(CCCCCCCCCC)CN=C(O)c1c(Br)c(Br)c(C(O)=NCC(CCCCCCCCCC)CCCCCCCCCCCC)c2c(C(=O)O)c(Br)c(Br)c(C(=O)O)c12

HCID178442862

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCC(CCCCCC)CCN=C(O)c1c(Br)c(Br)c(C(O)=NCCC(CCCCCC)CCCCCCCC)c2c(C(=O)O)c(Br)c(Br)c(C(=O)O)c12

HCID178443004

未命名化合物

收率 31%

PROCEDURE

实验过程

The same synthetic method for compound 22 was used except using 3-hexylundecyl amine instead of 2-decyltetradecyl amine, and the yield was 31% (calculated based on TBNDA as a starting material).

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e0564ee04c0f4d219a3fa2a4229f2abc
来源数据集: uspto-grants-2013_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08471021B2
来源说明: uspto-grants-2013_06

反应 SMILES

C(C(CCCCCCCCCCCC)CN=[C:14]([C:16]1[C:25]2[C:24]([C:26]([OH:28])=[O:27])=[C:23]([Br:29])[C:22]([Br:30])=[C:21]([C:31]([OH:33])=[O:32])[C:20]=2[C:19]([C:34](=[N:36][CH2:37][CH:38](CCCCCCCCCC)CCCCCCCCCCCC)[OH:35])=[C:18]([Br:61])[C:17]=1[Br:62])[OH:15])CCCCCCCCC.[CH2:75]([CH:81]([CH2:85][CH2:86][CH2:87][CH2:88][CH2:89][CH2:90][CH2:91][CH3:92])[CH2:82][CH2:83][NH2:84])[CH2:76][CH2:77][CH2:78][CH2:79][CH3:80]>>[CH2:75]([CH:81]([CH2:85][CH2:86][CH2:87][CH2:88][CH2:89][CH2:90][CH2:91][CH3:92])[CH2:82][CH2:83][N:84]=[C:14]([C:16]1[C:25]2[C:24]([C:26]([OH:28])=[O:27])=[C:23]([Br:29])[C:22]([Br:30])=[C:21]([C:31]([OH:33])=[O:32])[C:20]=2[C:19]([C:34](=[N:36][CH2:37][CH2:38][CH:81]([CH2:75][CH2:76][CH2:77][CH2:78][CH2:79][CH3:80])[CH2:85][CH2:86][CH2:87][CH2:88][CH2:89][CH2:90][CH2:91][CH3:92])[OH:35])=[C:18]([Br:61])[C:17]=1[Br:62])[OH:15])[CH2:76][CH2:77][CH2:78][CH2:79][CH3:80]