HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 2-Chloro-6-methyl-4-(2,5-dichloro-4-methylmercapto-phenoxy)-pyridine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | 2,4-Dichloro-6-methylpyridine | HCID 11959083 | — |
| Reactant | Potassium 2,5-dichloro-4-methylmercapto-phenolate | HCID 70505068 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 2-Chloro-6-methyl-4-(2,5-dichloro-4-methylmercapto-phenoxy)-pyridine | HCID 13073668 | — |
Reaction Steps
A solution of 25.5 gm (0.1 mol) of potassium 2,5-dichloro-4-methylmercapto-phenolate and 16.2 gm (0.1 mol) of 2,4-dichloro-6-methyl-pyridine in 100 ml of dimethylformamide was heated under reflux for 5 hours. It was then cooled and poured into 300 ml of water. The precipitate which separated out was recovered by suction filtration, washed with water, and recrystallized from isopropanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04453972 |
| Source dataset | uspto-grants-1984_06 |
| ORD ID | ord-e9c59a82f7d346e99ef65f079b634475 |
| Source note | uspto-grants-1984_06 |