HuagongsheHuagongshe Chemistry Print Report · For research reference only
Gemcadiol → 2,2,9,9-Tetramethyldecane-1,10-diyl dipyridine-3-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Gemcadiol | HCID 37147 | — |
| Reactant | 3-Pyridinecarbonyl chloride, hydrochloride (1:1) | HCID 88438 | — |
| Solvent | Pyridine | HCID 1049 | — |
| Product | 2,2,9,9-Tetramethyldecane-1,10-diyl dipyridine-3-carboxylate | HCID 3069676 | 65% |
Reaction Steps
106.2 Grams (0.6 mole) of nicotinoyl chloride hydrochloride in 300 ml of anhydrous pyridine were reacted with 23.0 grams (0.1 mole) of 2,2,9,9-tetramethyl-1,10-decanediol, according to the procedure described in Example 1. 28.8 Grams of product, recrystallized from ethanol, were obtained, having m.p. 68°-69° C. Yield: 65,5% of theoretical.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04454145 |
| Source dataset | uspto-grants-1984_06 |
| ORD ID | ord-0883ef58e7dd448d948e7b158bc10500 |
| Source note | uspto-grants-1984_06 |