HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylamine → Dimethylethylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylamine | HCID 674 | — |
| Reactant | Ethylene | HCID 6325 | — |
| Reactant | 1,4-Dioxane | HCID 31275 | — |
| Product | Dimethylethylamine | HCID 11723 | — |
| Product | Diethylmethylamine | HCID 12022 | — |
Reaction Steps
A mixture of 104 parts of 1,4-dioxane (inert solvent), 5.6 parts of dimethylamine and 0.363 parts (0.11 mol/mol C2H4) of [Ru(NH3)4 (OH)Cl]Cl.2H2O were placed in a 300 ml stainless steel autoclave. The autoclave was pressured with 200 psig of ethylene. A total of 0.12 parts of dimethylethylamine and 2.1 parts of diethylmethylamine were obtained corresponding to a conversion of 21% and a combined yield of 99% (based on dimethylamine).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04454321 |
| Source dataset | uspto-grants-1984_06 |
| ORD ID | ord-a483c0091c4f42f48e91851f4994973b |
| Source note | uspto-grants-1984_06 |