Phosphorus sulfide (P2S5) → HCID 20454847, compound

HRID 1263183Notes

Reaction equation

HRID 1263183 reaction equation
[CH2:1]([P:3]([C:14]1[CH:19]=[C:18]([O:20][C:21]2[CH:26]=[CH:25][C:24]([C:27]([F:30])([F:29])[F:28])=[CH:23][C:22]=2[Cl:31])[CH:17]=[CH:16][C:15]=1[N+:32]([O-:34])=[O:33])(=O)[O:4][CH2:5][O:6][C:7](=[S:12])[C:8]([CH3:11])([CH3:10])[CH3:9])[CH3:2].P12(SP3(SP(SP(S3)(S1)=S)(=S)S2)=S)=[S:36]>>[CH2:1]([P:3]([C:14]1[CH:19]=[C:18]([O:20][C:21]2[CH:26]=[CH:25][C:24]([C:27]([F:30])([F:29])[F:28])=[CH:23][C:22]=2[Cl:31])[CH:17]=[CH:16][C:15]=1[N+:32]([O-:34])=[O:33])(=[S:36])[O:4][CH2:5][O:6][C:7](=[S:12])[C:8]([CH3:11])([CH3:10])[CH3:9])[CH3:2]

Participants

3

Reactant 2

HCID 14817Phosphorus sulfide (P2S5)HCID 20454868HCID 20454868, compound

Product 1

HCID 20454847HCID 20454847, compound

Procedure

In the same way, 2,2-dimethyl(thiopropionyl)oxymethyl P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinate is reacted with phosphorus pentasulfide to yield O-[2,2-dimethyl(thiopropionyl)oxymethyl] P-ethyl-2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenylphosphinothioate.

Sources & evidence

ORD record
ord-e00ebae007774990a67a782c17217e4a
Source dataset
uspto-grants-1984_06
Patent number
US04456465

Reaction notes

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