Ammonia → HCID 57093790, compound
Reaction equation
C([S:4][CH2:5][C:6]([N:8]1[CH2:12][C:11]([CH2:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:10][C@H:9]1[C:20]([OH:22])=[O:21])=[O:7])(=O)C.N>>[SH:4][CH2:5][C:6]([N:8]1[CH2:12][C:11]([CH2:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:10][C@H:9]1[C:20]([OH:22])=[O:21])=[O:7]Participants
3
Procedure
The product from part (b) is treated with concentrated ammonia according to the procedure of Example 4 to yield (2S)-2,5-dihydro-1-(2-mercapto-1-oxoethyl)-4-(phenylmethyl)-1H-pyrrole-2-carboxylic acid.
Sources & evidence
- ORD record
- ord-f79d492d0c114c7aa192f7b4cc104a6b
- Source dataset
- uspto-grants-1984_06
- Patent number
- US04456761
Reaction notes
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