Ammonia → HCID 57036626, compound

HRID 1263371Notes

Reaction equation

C([S:4][CH2:5][CH2:6][C:7]([N:9]1[CH2:13][C:12]([CH2:14][CH2:15][CH2:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH:11][C@H:10]1[C:23]([OH:25])=[O:24])=[O:8])(=O)C.N>>[SH:4][CH2:5][CH2:6][C:7]([N:9]1[CH2:13][C:12]([CH2:14][CH2:15][CH2:16][C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)=[CH:11][C@H:10]1[C:23]([OH:25])=[O:24])=[O:8]

Participants

Reactant 2

HCID 222Ammonia

HCID 57018093HCID 57018093, compound

Product 1

HCID 57036626HCID 57036626, compound

Procedure

The product from part (b) is treated with concentrated ammonia according to the procedure of Example 4 to yield [2S]-2,5-dihydro-1-(3-mercapto-1-oxopropyl)-4-(phenylpropyl)-1H-pyrrole-2-carboxylic acid.

Sources & evidence

ORD record: ord-aab15e2673ed406ab7982be02b061d4b
Source dataset: uspto-grants-1984_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04456761

Reaction notes

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