HuagongsheHuagongshe Chemistry Print Report · For research reference only
Homogentisic Acid → Phytyl diphosphate(3-)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Homogentisic Acid | HCID 780 | — |
| Reactant | Phosphoric Acid | HCID 1004 | — |
| Reactant | (+)-gamma-Tocopherol | HCID 92729 | — |
| Reactant | Tocol, (2R)- | HCID 58866062 | — |
| Product | Phytyl diphosphate(3-) | HCID 71728454 | — |
| Product | Phytylplastoquinol | HCID 71768102 | — |
| Product | 2-Methyl-6-phytylquinol | HCID 71768135 | — |
Reaction Steps
Homogentisic acid in 0.1% H3PO4 (specific radioactivity 40 Ci/mmol). Phytyl pyrophosphate was synthesized as described by Joo, et al. (1973) Can J. Biochem. 51: 1527. 2-methyl-6-phytylquinol and 2,3-dimethyl-5-phytylquinol were synthesized as described bySoll, et al. (1980) Phytochemistry 19: 215. Homogentisic acid, α, β, δ, and γ-tocopherol, and tocol, were purchased commercially.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06541259B1 |
| Source dataset | uspto-grants-2003_04 |
| ORD ID | ord-a9de046f2e654de5b5db01ec8e69c814 |
| Source note | uspto-grants-2003_04 |