Phosgene → 3-Nitrophenyloxycarbonyl chloride

HRID 1264452Notes

Reaction equation

[N+:1]([C:4]1[CH:5]=[C:6]([OH:10])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[C:11](Cl)([Cl:13])=[O:12]>>[N+:1]([C:4]1[CH:5]=[C:6]([O:10][C:11]([Cl:13])=[O:12])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

Participants

Reactant 2

HCID 6371Phosgene

HCID 111373-Nitrophenol

Product 1

HCID 113331413-Nitrophenyloxycarbonyl chloride

Procedure

The 3-nitrophenyloxycarbonyl compound can be prepared by reaction of 3-nitrophenol with phosgene to yield 3-nitrophenyloxycarbonyl chloride. The latter can then be reacted with a thiol:

Sources & evidence

ORD record: ord-adb0139c296842d5880ea3c23b6036ea
Source dataset: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06544499B1

Reaction notes

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