Iron(2+) tetrafluoroborate--water (1/2/6) → Iron(II) tetrafluoroborate

HRID 1265274Notes

Reaction equation

HRID 1265274 reaction equation
O.O.O.O.O.O.[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]>ClCCl>[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]

Participants

3

Reactant 1

HCID 15762351Iron(2+) tetrafluoroborate--water (1/2/6)

Product 1

HCID 11736352Iron(II) tetrafluoroborate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Procedure

To a suspension of iron(II) bis(tetrafluoroborate) hexahydrate (4.9 mg; 15 μmol) in dichloromethane was added a solution of h17 (5.0 mg; 14 μmol) in a few milliliters of dichloromethane. The solution turned from light yellow to dark orange with time within 18 hours. The solution was used as is in further polymerization study.

Workup

  1. customwithin 18 hours

Sources & evidence

ORD record
ord-2e120f31d50341b7a2882bba00c0bdf9
Source dataset
uspto-grants-2003_04
Patent number
US06545108B1

Reaction notes

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