Oxygen → HCID 18551913, compound

Participants

Reaction Steps

A mixture of 20 mmol of dimethyl adipate, 2 mmol of 1-octene, 0.04 mmol of manganese(II) acetate, 0.002 mmol of cobalt (II) acetate and 2 ml of acetic acid was stirred at 90° C. in an atmosphere of a gaseous mixture of nitrogen and oxygen (9:1) (1 atm=0.101 MPa) for 3 hours. The resulting reaction mixture was analyzed to find that dimethyl 2-octyladipate and dimethyl 2,5-dioctyladipate were produced in yields of 36% and 2%, respectively, with a conversion from 1-octene of 60%.

Provenance & Evidence