Heptane, 1,1,1,2,2-pentafluoro-7-iodo- → Ethyl 2-(6,6,7,7,7-pentafluoroheptyl)-9-decenoate

HRID 1267749Notes

Reaction equation

HRID 1267749 reaction equation
[CH2:1]([CH:9]([C:15](OCC)=O)[C:10]([O:12][CH2:13][CH3:14])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].IC[CH2:22][CH2:23][CH2:24][CH2:25][C:26]([F:32])([F:31])[C:27]([F:30])([F:29])[F:28]>>[F:31][C:26]([F:32])([C:27]([F:28])([F:29])[F:30])[CH2:25][CH2:24][CH2:23][CH2:22][CH2:15][CH:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8])[C:10]([O:12][CH2:13][CH3:14])=[O:11]

Participants

3

Reactant 2

HCID 12017065Heptane, 1,1,1,2,2-pentafluoro-7-iodo-HCID 18546278Diethyl 2-(7-octenyl)malonate

Product 1

HCID 18546286Ethyl 2-(6,6,7,7,7-pentafluoroheptyl)-9-decenoate

Procedure

Starting with the diethyl 2-(7-octenyl)malonate prepared in Example 5 and the 1-iodo-6,6,7,7,7-pentafluoroheptane prepared in Example 3, the same procedure as shown in Example 5 was repeated to give ethyl 2-(6,6,7,7,7-pentafluoroheptyl)-9-decenoate.

Sources & evidence

ORD record
ord-bb5fde22e06e42a7b4a63da3a2bc2266
Source dataset
uspto-grants-2003_04
Patent number
US06552068B1

Reaction notes

Loading…