1,1,1,2,2-Pentafluoro-8-iodooctane → Ethyl 2-(7,7,8,8,8-pentafluorooctyl)-9-decenoate

HRID 1267750Notes

Reaction equation

HRID 1267750 reaction equation
[CH2:1]([CH:9]([C:15](OCC)=O)[C:10]([O:12][CH2:13][CH3:14])=[O:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].IC[CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][C:27]([F:33])([F:32])[C:28]([F:31])([F:30])[F:29]>>[F:32][C:27]([F:33])([C:28]([F:29])([F:30])[F:31])[CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:15][CH:9]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8])[C:10]([O:12][CH2:13][CH3:14])=[O:11]

Participants

3

Reactant 2

HCID 120170661,1,1,2,2-Pentafluoro-8-iodooctaneHCID 18546278Diethyl 2-(7-octenyl)malonate

Product 1

HCID 18546272Ethyl 2-(7,7,8,8,8-pentafluorooctyl)-9-decenoate

Procedure

Starting with the diethyl 2-(7-octenyl)malonate prepared in Example 5 and the 1-iodo-7,7,8,8,8-pentafluorooctane prepared in Example 4, the same procedure as shown in Example 5 was repeated to give ethyl 2-(7,7,8,8,8-pentafluorooctyl)-9-decenoate.

Sources & evidence

ORD record
ord-661880dd5edb4a62bfc1fe58ea8bb6e5
Source dataset
uspto-grants-2003_04
Patent number
US06552068B1

Reaction notes

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