1,1,1,2,2-Pentafluoro-5-iodopentane → Ethyl 2-(4,4,5,5,5-pentafluoropentyl)-8-nonenoate

HRID 1267753Notes

Reaction equation

HRID 1267753 reaction equation
[CH2:1]([CH:8]([C:14](OCC)=O)[C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7].IC[CH2:21][CH2:22][C:23]([F:29])([F:28])[C:24]([F:27])([F:26])[F:25]>>[F:28][C:23]([F:29])([C:24]([F:27])([F:26])[F:25])[CH2:22][CH2:21][CH2:14][CH:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7])[C:9]([O:11][CH2:12][CH3:13])=[O:10]

Participants

3

Reactant 2

HCID 120170571,1,1,2,2-Pentafluoro-5-iodopentaneHCID 18546274Diethyl 2-(6-heptenyl)malonate

Product 1

HCID 12043782Ethyl 2-(4,4,5,5,5-pentafluoropentyl)-8-nonenoate

Procedure

Starting with the diethyl 2-(6-heptenyl)malonate prepared in Example 9 and the 1-iodo-4,4,5,5,5-pentafluoro-pentane prepared in Example 1, the same procedure as shown in Example 5 was repeated to give ethyl 2-(4,4,5,5,5-pentafluoropentyl)-8-nonenoate.

Sources & evidence

ORD record
ord-c8f40668fef74c72a0af7fe9269f98ad
Source dataset
uspto-grants-2003_04
Patent number
US06552068B1

Reaction notes

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