Heptane, 1,1,1,2,2-pentafluoro-7-iodo- → Ethyl 2-(6,6,7,7,7-pentafluoroheptyl)-8-nonenoate

HRID 1267754Notes

Reaction equation

HRID 1267754 reaction equation
[CH2:1]([CH:8]([C:14](OCC)=O)[C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7].IC[CH2:21][CH2:22][CH2:23][CH2:24][C:25]([F:31])([F:30])[C:26]([F:29])([F:28])[F:27]>>[F:30][C:25]([F:31])([C:26]([F:27])([F:28])[F:29])[CH2:24][CH2:23][CH2:22][CH2:21][CH2:14][CH:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7])[C:9]([O:11][CH2:12][CH3:13])=[O:10]

Participants

3

Reactant 2

HCID 12017065Heptane, 1,1,1,2,2-pentafluoro-7-iodo-HCID 18546274Diethyl 2-(6-heptenyl)malonate

Product 1

HCID 22718078Ethyl 2-(6,6,7,7,7-pentafluoroheptyl)-8-nonenoate

Procedure

Starting with the diethyl 2-(6-heptenyl)malonate prepared in Example 9 and the 1-iodo-6,6,7,7,7-pentafluoro-heptane prepared in Example 3, the same procedure as shown in Example 5 was repeated to give ethyl 2-(6,6,7,7,7-pentafluoroheptyl)-8-nonenoate.

Sources & evidence

ORD record
ord-3af4ce5bb2a64281b4f576bb77f933ae
Source dataset
uspto-grants-2003_04
Patent number
US06552068B1

Reaction notes

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