1,1,1,2,2-Pentafluoro-8-iodooctane → Ethyl 2-(7,7,8,8,8-pentafluorooctyl)-8-nonenoate

HRID 1267755Notes

Reaction equation

HRID 1267755 reaction equation
[CH2:1]([CH:8]([C:14](OCC)=O)[C:9]([O:11][CH2:12][CH3:13])=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7].IC[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][C:26]([F:32])([F:31])[C:27]([F:30])([F:29])[F:28]>>[F:31][C:26]([F:32])([C:27]([F:28])([F:29])[F:30])[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:14][CH:8]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH:6]=[CH2:7])[C:9]([O:11][CH2:12][CH3:13])=[O:10]

Participants

3

Reactant 2

HCID 120170661,1,1,2,2-Pentafluoro-8-iodooctaneHCID 18546274Diethyl 2-(6-heptenyl)malonate

Product 1

HCID 18546271Ethyl 2-(7,7,8,8,8-pentafluorooctyl)-8-nonenoate

Procedure

Starting with the diethyl 2-(6-heptenyl)malonate prepared in Example 9 and the 1-iodo-7,7,8,8,8-pentafluoro-octane prepared in Example 4, the same procedure as shown in Example 5 was repeated to give ethyl 2-(7,7,8,8,8-pentafluorooctyl)-8-nonenoate.

Sources & evidence

ORD record
ord-b2cff204c8e642c19c407f5895b743ba
Source dataset
uspto-grants-2003_04
Patent number
US06552068B1

Reaction notes

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