HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisobutylaluminum hydride → (E)-3-(2',3'-dichloro-biphenyl-4-yl)-but-2-en-1-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisobutylaluminum hydride | HCID 14487 | — |
| Reactant | (E)-Ethyl 3-(2',3'-dichloro-biphenyl-4-yl)-but-2-enoate | HCID 22557696 | — |
| Product | (E)-3-(2',3'-dichloro-biphenyl-4-yl)-but-2-en-1-ol | HCID 69801043 | — |
Reaction Steps
(E)-Ethyl 3-(2′,3′-dichloro-biphenyl-4-yl)-but-2-enoate (1.07 g, 3.19 mmol) was reduced with DIBAL-H by a procedure analogous to that described in example 52b to give (E)-3-(2′,3′-dichloro-biphenyl-4-yl)-but-2-en-1-ol as a colourless solid; 0.74 g (79%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06555577B1 |
| Source dataset | uspto-grants-2003_04 |
| ORD ID | ord-0c72a5e9f3fc47ed907e487883bcabc9 |
| Source note | uspto-grants-2003_04 |