HCID 131726315, compound → 13463-39-3
Reaction equation
[C:1](=O)([O-])[O-:2].[Ni+2].[Ni:6](Cl)Cl.[H][H].[C]=O>>[C-:1]#[O+:2].[C-:1]#[O+:2].[C-:1]#[O+:2].[C-:1]#[O+:2].[Ni:6]Participants
4
Conditions
- Temperature
- 40 °C
Procedure
300.1 g of a nickel carbonate/nickel chloride mixture (10:1 w/w) was placed into an extraction reactor and treated with hydrogen (2 L/min) at 450° C. for 6 hours. Subsequently, the hydrogen was replaced with argon, the reactor cooled to 40° C. and the argon replaced with carbon monoxide at a gas temperature of 80° C., and flow rate of 4 L/min. whereby nickel carbonyl was formed, collected and subsequently decomposed to Ni and CO to provide (103 g; 70%) yield of nickel extraction yield in 6 hr.
Sources & evidence
- ORD record
- ord-5f02323f5afb4589b31fe06988d5be29
- Source dataset
- uspto-grants-2007_04
- Patent number
- US07198770B2
Reaction notes
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