HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methane → 1,1,1-Trichloro-4-methylpent-3-en-2-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methane | HCID 297 | — |
| Reactant | 1,1,1-Trichloro-4-methylpent-4-en-2-ol | HCID 91391 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 1,1,1-Trichloro-4-methylpent-3-en-2-ol | HCID 3014424 | 59.2% |
Reaction Steps
1,1,1-Trichloro-4-methyl-4-penten-2-ol (74 g, 0.36 mole) was heated at 140°-150° for 18 hours. After cooling, the alcohol was diluted with ether, and the ethereal solution was treated with activated charcoal. The ether was removed by evaporation to afford crystalline 1,1,1-trichloro-4-methyl-3-penten-2-ol (43.4 g, 59% yield) after recrystallization from petroleum ether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04254282 |
| Source dataset | uspto-grants-1981_03 |
| ORD ID | ord-66d15e8eece9472384101feb37d29310 |
| Source note | uspto-grants-1981_03 |